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EPSRC PhD Studentship - Hydrogen Production by Electrolysis of Aqueous Alcohols![]() Postgraduate OpportunitiesNewcastle UniversitySubjects: Chemical Engineering
Supervisor(s): Professor Keith Scott In water electrolysis, for example using a proton exchange membrane (PEM) cell, hydrogen is produced at the cathode by reduction of protons (H+) which are formed at the anode during oxygen evolution. Similar electrolysis process to produce hydrogen can use a range of other organic and waste materials; sugars etc. For alcohols hydrogen is produced: Ethanol: C2H5OH + 3 H2O →2 CO2 + 6 H2 The advantage of using an alcohol such as methanol is that the theoretical cell potential, based on standard electrode potentials for water oxidation and methanol oxidation, is some 1.2 V lower than for water electrolysis. The theoretical operating potential of the cell is 0.02 V, i.e. 20 mV to convert 1 mole methanol to 3 moles hydrogen. For this project, we are interested in developing novel catalysts for hydrogen production, and oxygen evolution with low overpotentials. Also, the design and optimisation of PEM cell configuration will be investigated for the specific purpose of hydrogen production. Person Specification Value of the Award and Eligibility How to Apply Closing date: Candidates are encouraged to apply as soon as possible as this position will be filled as soon as a suitable candidate is found. Further Information Funding information
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